Stepwise reactions of TiCl4 and Ti(OiPr)Cl3 with 2-propanol. Variable-temperature NMR studies...Reports on the stepwise reactions of titanium chloride and Ti(OiPr)Cl3 with 1-3 molar equivalent of 2-propanol. Synthesis of complexes; X-ray structural analysis of molecular structures; Selected ...
The initial stages of chemical vapor deposition of TiSi2 from TiCl4, H2, and Si(100) have been investigated with respect to the phase formation sequence. The result showed that the metastable C49 TiSi2 phase was formed prior to the equil... J Engqvist,U Jansson,J Lu,... - 《Journal ...
2.(1)OF 的熔、沸点低于(填“高于”或“低于”)Cl2O,原因是(2)Ti的四卤化物熔点如下表所示,TiF4熔点高于其他三种卤化物,自TiCl4至TiI熔点依次升高,原因是O化合物TiF TiCl4TiBr Til熔点/℃377-24.1238.3155(3)Cu、Zn等金属具有良好的导电性,从金属键的理论看,原因是自由电子在外加电场中作定向移动(4)卤化...
Treatment of TiCl4(THF)2 with 3.0 equiv of (t)Bu3SiNHLi in Et2O produced ((t)Bu3SiNH)3TiCl (1; 82%). An attempt to alkylate 1 with MeMgBr led to ((t)Bu3SiN... CC Cummins,CP Schaller,GD Van Duyne,... - 《Journal of the American Chemical Society》 被引量: 639发表: 1991年...
Crystal StructureCl3Ti[N(SiMe2Cl)(SiMe2NH2)] is yielded by reaction of TiCl4 with two molecules ClMe2SiNHSiMe3. A single crystal structure determination (P 21/n, a = 747.12(2), b = 1294.1(3), c = 1496.7(3) pm, β = 90.30(3)°, Z = 4) shows a planar four-membered ring ...
机译:水分解:通过TiCl4处理的3D掺锑SnO2大孔/支化α-Fe2O3纳米棒异质结光电阳极实现高效的光电化学水氧化(Adv。Sci。7/2015) 7. Substrate Dependent Water Splitting with Ultrathin α‑Fe_2O_3 Electrodes [O] . Zandi Omid, Beardslee Joseph A., Hamann Thomas 2014 ...
Achieving Highly Efficient Photoelectrochemical Water Oxidation with a TiCl4 Treated 3D Antimony-Doped SnO2 Macropore/Branched -Fe2O3 Nanorod Heterojunctio... Utilizing photoelectrochemical (PEC) cells to directly collecting solar energy into chemical fuels (e.g., H2 via water splitting) is a promisi...
Dimethylsilylene bridged 3,4-dimethylcyclopentadienyl/amido titanium and zirconium complexes, namely [Me2Si(C5Me2H2)(tBuN)]MCl2 (M=Ti, Zr), were synthesized by the reactions of the dilithium salt of the ligand with the corresponding inexpensive metal precursors TiCl4(THF)2 and ZrCl4, ...
Towards supported catalyst models: the synthesis, characterization, redox chemistry, and structures of the complexes Ti(OAr′)4 (Ar′ = C6H4(2-t-Bu), C6H(2... Reaction of substituted phenoxides with TiCl4 affords the species Ti(OAr′)4 (Ar′ = C6H4(2-t-Bu), 1; Ar′ = C6H(2,...
A series of titanium(IV) acetylacetonate (acac) complexes, Ti(acac)Cl3 (THF) (2), [Ti(acac)Cl2(THF)]2 (μ-O) (3), [Ti(O-i-Pr)Cl3(acac)]-(HNEt3+) (5), and Ti(O-i-Pr)Cl2 (acac)(THF) (6), were prepared from reactions of TiCl4 or Ti(O-i-Pr)Cl3 with 2,4-...