A novel method was proposed to produce TiH2 from the reduction of titanium tetrachloride (TiCl4) with magnesium hydride (MgH2) in the hydrogen (H2) atmosphere. The primary approach of this process is to produce TiH2 at a low-temperature range through an efficient and energy-saving process for...
Treatment of TiCl4(THF)2 with 3.0 equiv of (t)Bu3SiNHLi in Et2O produced ((t)Bu3SiNH)3TiCl (1; 82%). An attempt to alkylate 1 with MeMgBr led to ((t)Bu3SiN... CC Cummins,CP Schaller,GD Van Duyne,... - 《Journal of the American Chemical Society》 被引量: 641发表: 1991年...
Reaction of substituted phenoxides with TiCl4 affords the species Ti(OAr′)4 (Ar′ = C6H4(2-t-Bu), 1; Ar′ = C6H(2,3,5,6-Me)4, 2). The compound Ti(OC6H4(2-t-Bu))4, 1, crystallizes in the tetragonal space group , with a = 15.203(4) , c = 8.026(3) , Z = 2, ...
Crystal StructureCl3Ti[N(SiMe2Cl)(SiMe2NH2)] is yielded by reaction of TiCl4 with two molecules ClMe2SiNHSiMe3. A single crystal structure determination (P 21/n, a = 747.12(2), b = 1294.1(3), c = 1496.7(3) pm, β = 90.30(3)°, Z = 4) shows a planar four-membered ring ...
机译:双组分Ti(acac)(2)Cl-2-Et2AlCl体系催化7-烷基(烯丙基,苯基)-1,3,5-环庚烯与含Si炔烃的反应,形成取代的以高收率完成了双环[4.2.1]壬基-2,4,7-三烯的合成。所获得的化合物的结构通过H-1,C-13 NMR光谱确认。通过在B3LYP / 6-31G(d)水平上环庚三烯和乙炔与TiCl4-Et2AlCl体系的相互作用...
The titanium compound (C5Me4Ph)TiCl3 (1) can be prepared by the reaction of (C5Me4Ph)SiMe3 with TiCl4. Hydrolysis of 1 in the presence of HNEt2 or Ag2O has allowed for the isolation of the oxochloride complexes [(C5Me4Ph)TiCl2]2(μ-O) (2... Mar,Bjrgvinsson,and,... - 《...
TiCl4/MgH2-supported Ziegler-type catalyst system, 2. Effect of Ti concentration, Ti content and surface area of TiCl4/MgH2 catalyst on the concentration of active sites in ethylene polymerizationaetiologyage groupsantibodiesbacterial diseases
TiCl4 was used to coat TiO2 NPs with a nanoscale compact thin TiO2 layer against charge recombination with oxidised species in electrolyte. A consecutive layer of CdSe nanoparticles was induced by successive ionic layer adsorption and reaction (SILAR) mode for sensitisation by light harvesting. J-V...
A series of titanium(IV) acetylacetonate (acac) complexes, Ti(acac)Cl3 (THF) (2), [Ti(acac)Cl2(THF)]2 (-O) (3), [Ti(O-i-Pr)Cl3(acac)]-(HNEt3+) (5), and Ti(O-i-Pr)Cl2 (acac)(THF) (6), were prepared from reactions of TiCl4 or Ti(O-i-Pr)Cl3 with 2,4-...
A series of titanium(IV) acetylacetonate (acac) complexes, Ti(acac)Cl3 (THF) (2), [Ti(acac)Cl2(THF)]2 (μ-O) (3), [Ti(O-i-Pr)Cl3(acac)]-(HNEt3+) (5), and Ti(O-i-Pr)Cl2 (acac)(THF) (6), were prepared from reactions of TiCl4 or Ti(O-i-Pr)Cl3 with 2,4-...