H. The mechanism of octahedral complex formation by labile metal ions. Coordination Chemistry Rev. 5, 45-73 (1970).D.J. Hewkin, R.H. Prince, The mechanism of octahedral complex formation by labile metal ions, Coord. Chem. Rev. 5 (1970) 45....
Caneschi, A.; Cornia, A.; Lippard, S. J., A Cyclic Hexairon(III) Complex with an Octahedrally Coordinated Sodium Ion at the Center, an Example of the [12]Metallacrown-6 Structure Type. Angewandte Chemie International Edition in English 1995, 34 (4), 467-469....
The 1st row transition metals (Sc–Co), the Fe group (Ru, Os) and Mo, all of these with a preference for + 3 oxidation states and octahedral (Oh) geometry, were examined. Frontier molecular orbital analysis The ground state reactivity was analyzed for amphibactin–transition metal ion ...
01 April 2016 Key role of lattice symmetry in the metal-insulator transition of NdNiO3 films Jack Y. Zhang, Honggyu Kim, Evgeny Mikheev, Adam J. Hauser & Susanne Stemmer Bulk NdNiO3 exhibits a metal-to-insulator transition (MIT) as the temperature is lowered that is also...
The zincophosphite is purly inorganic with the octahedral zinc complex filled in the channel. The synthesis of system required the presence of the organic amine which is not incorporated into the structure of the product. The framework-metal complex encapsulating in the channel is the first time ...
which is capable of removing multivalent ions and other organic molecules while allowing free water movement. Applying these membranes for monovalent ion removal would be achievable if the space were tuned below the sizes of the hydrated ions1,79,80. Monovalent ion separation using a membrane-based...
The electrochemical characteristics of spinel shape structures arise because they can accommodate a wide range of multiple oxidation states cations in their tetrahedral and octahedral sites. Such atomic configurations and coordination dictate the catalytic ORR−OER [13]. Spinel-type transition metal ...
When the spinel structure is interrupted by a surface, octahedral B sites are more exposed than tetrahedral A sites. As a consequence, B sites have been considered to represent the most effective catalytic sites [1]. However, this assumption has somehow to be qualified, as the internal charge...
Here, we present the synthesis and characterizationof the heptanuclear complex [{(talent-Bu2)MnIII3}2-{CoIII(CN)6}]3+++([MnIII6CoIII]3+++), which is the firstmember of the heptanuclear triplesalen complex fam-ily with a diamagnetic central metal ion. The detailedmagnetic characterization...
The catecholate group provides two oxygen atoms for chelation with iron so that a hexadentate octahedral complex is formed as in the hydroxamate siderophores [25]. The finest example for catecholate siderophore is enterobactin produced by Escherichia coli. Carboxylate siderophores are produced by ...