The preparation of a series of half-sandwich ruthenium complexes, [RuCl2(eta(6)-p-cymene)-(P*)] (P* = S-PMeRR') and [RuCl2(kappa-P*-eta(6)-arene)], containing P-stereogenic phosphines is reported. The borane-protected P-stereogenic phosphines have been obtained by addition of...
1402448-57-0 Basic Information Chemical Name[Ru(II)Cl(eta6-p-cymene)(kappa2N,N'-bis(pyrazol-1-yl)acetic acid)](1+) CAS No.1402448-57-0 Molecular FormulaC18H22ClN4O2Ru Molecular Weight462.92 PSA91.48000 LogP2.60450 View More1402448-57-0 Properties ...
The novel water-soluble ruthenium(II) complexes [RuCl2(η6-arene){P(CH2OH)3}]2a–c and [RuCl(η6-arene){P(CH2OH)3}2][Cl]3a–c have been prepared in high yields by reaction of dimers [{Ru(η6-arene)(μ-Cl)Cl}2](arene = C6H61a, p-cymene 1b... V Cadierno,P Crochet,SE ...
Syntheses of (eta(6)-p-cymene) ruthenium(II) piano-stool amine complexes: molecular structure of (eta(6)-C10H14)RuCl2(H2N-C6H4-p-Cl) The dimeric complex [{(η6-p-cymene)Ru(μ-Cl)Cl}2] (1) reacts with S,N-donor Schiff base ligands, para-substituted S-(thiophen-2-ylmethylene)...
Synthesis, characterization, and in vitro evaluation of novel ruthenium(II) eta6-arene imidazole complexes. Ten complexes of general formula [Ru(eta6-arene)Cl2(L)], [Ru(eta6-arene)Cl(L)2][X], and [Ru(eta6-arene)(L)3][X]2 (eta6-arene = benzene, p-cymene; L = imida......
Synthesis and characterization of some arene hydrido-complexes [Ru(eta(6)-arene)(EPh3)(2)H](+) (eta(6)-arene = benzene, p-cymene or hexamethylbenzene; E = ... [{Ru(η6-arene)Cl2}2] (η6-arene=benzene, p-cymene or hexamethylbenzene) reacts with EPh3 (E=P, As or Sb) ...
Direct Preparation of [Ru(η2-O2CO)(η6-arene)(L)] Carbonate Complexes (L = Phosphane, Carbene) and Their Use as Precursors of [RuH2(p-cymene)(PCy3)] and [... [RuCl2(6-arene)(PR3)] complexes react with K2CO3 in the presence of water to afford the carbonatoruthenium( II ) ...
机译:双核[{(p-cym)RuCl} _2(μ-phpy)](PF_6)_2和异双核[[ppy)_2Ir(μ-phpy)Ru(p-cym)Cl](PF_6)_2配合物:合成,结构和抗癌活性 2. A dinuclear [{(p-cym)(RuCl)-Cl-II}(2)(mu-bpytz(center dot-))](+) complex bridged by a radical anion: synthesis, spectroelectrochemical, EP...
SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL STRUCTURES OF DICHLOROBIS(1,2-BIS(DIPHENYLPHOSPHINO... The reaction of trans-RuCl2(dppe)2 (1), with AgBF4 in tetrahydrofuran leads to abstraction of one of the halide ligands to produce the trigonal-bipyrimidal... JR Polam,LC Porter - 《...
机译:双重去质子化的1,1'-双(邻-碳硼烷)与[RuCl2(对-cymene)](2)反应得到[Ru(kappa(3)-2,2',3'-{1-(1) '-1',2'-closo-C2B10H10)-1,2-closo-C2B10H10})(对伞花烃)](1),其中1,1'-双(邻-碳环烷)充当X-2 (C,C')L配体,其中“ L”是B3'-H3'-> Ru B-亲和力相互作用,在298 K...