phosphanido ligandphosphinidene ligandThe reaction of polymeric [CpZrCl 3 ] n with solvent-free LiPH t Bu yields the trinuclear Zr III /Zr IV complex CpZr(μ-PH t Bu) 2 (μ-P t Bu) 2 {Zr(μ-Cl)Cp} 2 ( 1 ) in a redox reaction in low yield. The oxidation product (PH t ...
No abstract is available for this article.von Held, WernerBonnVöhringer, O.KarlsruheHaug, A.BerlinSchmidt, H.BonnJohn Wiley & Sons, Ltd.Physikalische Blätter
Coordination, deprotonation, rearrangement, and cleavage of Ph2PN(iPr)P(Ph)N(iPr)H (1) by trialkylaluminum compounds R3Al (R=Me, Et) are reported that are relevant to the selective ethene trimerization system consisting of the ligand 1, CrCl3(THF)3 and Et3Al that produces 1-hexene in ...
Copper and Silver Clusters with Bridging Imido and Amido LigandsFrom the reactions of copper and silver chloride with tertiary phosphines and lithiated aniline the compounds [{Li(dme)3}4][Cu18(NPh)11] (1) and [Ag6(NHPh)4(PnPr3)6Cl2] (2) were obtained. The structure o...