New complex salts [Pd(NH3)(4)][Pd(NH3)(3)NO2][CrOx(3)]center dot H2O I, [Pd(NH3)(4)][Pd(NH3)(3)NO2][CoOx(3)]center dot H2O II, and a series of solid solutions [Pd(NH3)(4)][Pd(NH3)(3)NO2][CoOx(3)](x)[RhOx(3)](1-x)center dot H2O III-V (Ox = C2O42-...
Crystal structures of [Pd(L1)2]Cl2·H2O, [Pt(L1)2](PF6)2 and [Pd3(L1)4Cl2]Cl4... The palladium(II) and platinum(II) complexes of 1-thia-4,7-diazacyclononane (L1) [Pd(L1)2]Cl2·H2O, [Pt(L1)2](PF6)2 and [Pd3(L1)4Cl2]Cl4·2H2O have been pr... HR Mattes - ...
Crystal structures of [L2Zn](PF6)2, [L'Zn(O2CPh)2(H2O)], [L'2Zn2(.mu.-OH)2](ClO4)2, and [L'... Canty AJ, Jin H, Skelton BW et al (1998) Oxidation of complexes by (O2CPh)2 and (ER)2 (E = S, Se), including structures of [cyclic] Pd(CH2CH2CH2CH2)(SePh)2(bpy...
64、Pligand:2.5 mol % PdCl2(CH3CN)27.5 mol % ligand2.5-.5 eq. Cs2CO3ArXR1.3-1.5 eq.+H2O/CH3CN (1:1)60-100 oC, 8-12 hRSO3Naligand:X: Br, ClArPCy22 mol % Pd(OAc)2 or Pd2(dba)2RXR+1.5 eq. Bu4NOAcDMF, r.t., 3-24 hRRX = I, Br J. Org. Chem., 2004, 69, 5752...
Substance Product name: SPhos Pd G2 Synonyms: SPhos Pd G2,RK1001022 CAS: 1375325-64-6 MF: C38H44ClNO2PPd+ MW: 719.608SECTION 4: First aid measures Description of first aid measures If inhaled Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing...
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Figure 1. Simplified scheme of proposed catalytic cycle taking place while using Pd/HPS in S-M cross-coupling between BrAn (designated here as Br-Ph-OCH3) and PBA (Ph-B(OH)2) resulting in formation of 4-methoxybiphenyl (designated here as (Ph)2-OCH3). In many works [4,6,14,15...
1b2a 2a 2b 2b 3b 3b PPdd11––CXl11– Pd1–N1– PPd1–1O–N2 2– N1–C1 – C1–C6 C61–.O41843(11) CC6l11––.N3P24d31–8N(128) X–1P.d419–9N71(119) N2–Pd1–N1 N11–.P2d219–5C(l117) CX–l11P–.d3P13d–71N–32X(1118) 1 X = Cl2 (2–a,b), O2 (3b)....
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