In contrast, reaction of 6a,cwith AgBF4in toluene or CH2Cl2yields the neutral solvent-free BF4adducts (3-C3H5)PdC(N(tBu)CH)2(BF4) (12a) and (3-C3H5)PdC(N(C6H3-2,6-iPr2)CH)2(BF4) (12c), consistent with the marked nucleophilicity of the BF4anion. Drying the CH2Cl2-solvates ...
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b Percentage of S100A9+ cells (left) and PD-L1+ cells (right) in PBMC from healthy donors (HD, n = 5) and patients with hepatocellular carcinoma (HCC, n = 7), colorectal cancer (CRC, n = 5), and biliary tract cancer (BTC, n = 7). c-e PD-L1 levels in ...
coupling reaction between 4-bromoacetophenone and phenylboronic acid in step I, and subsequently, Scientific Reports | Vol:.(1234567890) (2021) 11:9305 | https://doi.org/10.1038/s41598-021-88528-6 4 www.nature.com/scientificreports/ Entry 1 2 3 4 5 6 7 8b 9c 10c 11c,d 12c,d Cat...
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The co-condensation reaction of atomic palladium with a dilute CO–argon mixture (1:1000) at 10°K yields intermediate carbonyls of palladium Pd(CO)n where n = 1–3 as well as very small amounts of Pd(CO)4. Isotopic substitution experiments using 12C18O were used to aid the spectral ...