ca. 0.2–1.2 g of activated MS per mmol of alcohol areadded in order to accelerate the reaction. In order to moderate the acidity ofPCC, it is very common to add
PCC oxidation of alcohols is a commonly used method in organic chemistry to convert primary or secondary alcohols into aldehydes or ketones, respectively. This reaction is often preferred over other methods due to its mild conditions and highefficiency. PCC, or pyridinium chlorochromate, is a conveni...
Mechanism For The Oxidation Of Primary Alcohols To Aldehydes With Pyridinium Chlorochromate How does it work? Oxidation reactions of this sort are actually a kind of elimination reaction. We’re going from a carbon-oxygen single bond to a carbon-oxygen double bond. [See: Demystifying Alcohol Oxida...
Beside their main function of mediating the assembly and stability of the phycobilisomes, linker proteins also promote energy transfer towards the reaction centres [20]. Guillardia theta is a cryptophyte possessing phycoerythrin as a phycobiliprotein. The β-subunit is encoded on the plastid genome...
Additionally, glycogen synthesis by ADP-glucose phosphorylase (AGPase) coded by glgC is allosterically activated by 3-phosphoglycerate (3PGA), a product of carboxylating reaction by RuBisCO31. The downregulation of RuBisCO under high CO2 thus would also lead to decreased AGPase activity and glycogen ...
The identical cell samples used for proteomics analysis were used for RT-qPCR analysis. cDNAs were synthesized using RevertAidTM Reverse Transcriptase (Fermentas, Glen Burnie, MD, USA). The qPCR reaction was carried out in 20 μL reactions containing 10 μL of SYBR® Green PCR Master Mix (...
Because the energy gap of ΔG = +7 meV between [P700+A0−] and LWC* is close to this difference, the energy levels of [P700A0]* and [P700+A0−] match each other with high precision. A flat adiabatic term along the reaction coordinate for transition [P700A0]* ↔ [P700+A0−...