Recent works have expanded upon this observation, highlighting the proclivity of olefinic compounds to form stable intermediates often complemented by oxygen-containing functional groups [20]. Specifically, the electron delocalization of olefins facilitates H-atom abstraction and lends to favorable metastable...
The temperature (135 °C, 140 °C and 145 °C), the oxygen partial pressure (0.1 atm, 0.2 atm and 0.4 atm) and the catalyst concentration (1 ppm, 10 ppm and 100 ppm of Co) have been varied. An overall kinetic equation for the disappearance of hydrocarbon was determined and the ...
Calculate the mass of CO2emitted (in lbs) when 1 gallon of octane is burned. Combustion Reaction: A combustion reaction is a specific type of chemical reaction that involves the burning of hydrocarbons in the presence of oxygen to produce carbon dioxide and water. Sometimes the hydrocarbon...
There is an equation in which a molecule is treated with methanol in an acetone solution. Would the reaction be SN1 or SN2? I thought that it was SN2 because of the aprotic acetone, but the answer was a rac For which pairs of compounds would you n...
Gold-Catalyzed Addition of Oxygen Nucleophiles to C-C Multiple Bonds, in Catalyzed Carbon-Heteroatom Bond Formation (ed Yudin, A. K.) (Wiley-VCH Verlag GmbH & Co. KGaA, 2010). 45. Barluenga, J., Die´guez, A., Ferna´ndez, A., Rodrı´guez, F. & Fan˜ana´s, F...
(2) by comparison with 1 H and 13 C NMR spectra of the corresponding oxygen analog of heterobrendane; (3) by the calculation of the vicinal constants for the spin-spin interaction in the molecules of both analogs by the MMX program; and (4) by transformation into N-(p-bromo...
All the non-bridging oxygen atoms on the surface are fully protonated, and the surface has no net charge. Considering abundant nanopores in the size range of 3–8 nm in unconventional reservoir [33], the width of nanoslit is 5 nm. The CLAYFF force field [34] is implemented for α-...