Chemistry of metal hydrides. VII. An iridium(III) carbonyl cation and ...IrCl3(PEt3)3 is readily converted to IrHCl2(CO)(PEt3)2 by treatment with carbon monoxide in hot acetone, ethanol, or 2-methoxyethanol. Perchlorate, tetrafluoroborate, and tetraphenylborate salts containing the [IrCl2(CO...
Contributions to the impurity concentrations were also made by the hydrides. Furthermore, the MOCVD process is very sensitive to oxygen (more so than LPE and VPE) and the quality of the films is degraded when small oxygen leaks exist in the reactor system. Oxygen incorporation also contributes ...
Interactive 3D chemistry animations of reaction mechanisms and 3D models of chemical structures for students studying University courses and advanced school chemistry hosted by University of Liverpool
Transition metal hydrides (M-H) are ubiquitous intermediates in a wide range of enzymatic processes and catalytic reactions, playing a central role in H+/H2 interconversion1, the reduction of CO2 to formic acid (HCOOH)2 and in hydrogenation reactions. The facile formation of M-H is a critical...
(C3H7)2Te), and hydrides (H2S and H2Se)[13,46]. Similarly, for layeredtopological insulatorsBi2Se3and Bi2Te3, (CH3)3Bi is an ideal precursor for providing Bi. Several compounds in the liquid form have also been used for the synthesis of TMD monolayers[54,55], including (t-BuN=)2W...
A. Catalytic (de)hydrogenation promoted by non-precious metals — Co, Fe and Mn: recent advances in an emerging field. Chem. Soc. Rev. 47, 1459–1483 (2018). Article CAS PubMed Google Scholar Morris, R. H. Iron group hydrides in Noyori bifunctional catalysis. Chem. Rec. 16, 2644–...
This disclosure relates to novel metal hydrides, processes for their preparation, and their use in hydrogen storage applications.
hydridesmatrix isolationstannanesstructure elucidationIR measurements show that co-condensation of Al or Ga atoms (M) with SnH4 in a solid Ar matrix at about 12 K results mainly in the spontaneous insertion of the metal into an SnH bond to form the MII hydride HMSnH3. Simultaneously the Ga2...
Bimetallic complexes of rhenium multihydrides with silver, copper or mercury containing diphosphine ligands J. CHEM. SOC. DALTON TRANS. 1991 1025Bimetallic Complexes of Rhenium Multihydrides with Silver,Copper or Mercury containing Diphosphine LigandsStuart W. Carr, Xavier L. R. Fontaine and Bernard...
Stock, Hydrides of Boron and Silicon, Cornell 35 U. Press 1933, page 20. Hackh's, Chemical Dictionary, Blakiston (Phila.) 1937, 2nd ed. page 847.