2.2.1 1,3,5-均苯三甲酸合铜(Cu-BTC)的合成[21] 分别将0.87 g Cu(NO3)2·3H2O(3.6 mmol)溶于10 mL水中,0.22 g 1,3,5-均苯三甲酸(BTC)(1.0 mmol)溶于10 mL 乙醇中。然后将Cu(NO3)2溶液快速加入BTC溶液中,室温下连续搅拌10 min,向混合溶液中加入1 mL DMF。混合溶液于室温下搅拌反应12 h,将...
Magnetic and EPR data have been collected for complex [Cu(L-Arg)2](NO3)2·3H2O (Arg=arginine). Magnetic susceptibility χ in the temperature range 2–160 K, and a magnetization isotherm at T=2.29(1) K with magnetic fields between 0 and 9 T were measured. The observed variation...
Cu+2+2 (×1)11.9 🛠️ Calculate Oxidation Numbers Instructions Enter the formula of a chemical compound to find the oxidation number of each element. A net ionic charge can be specified at the end of the compound between { and }. For example: ZnCl4{2-} or NH2NH3{+}. ...
Low-Temperature Magnetization of Cu(NO[sub 3])[sub 2] [center-dot] 2.5H[sub 2]O We have measured magnetization isotherms for single crystals of monoclinic Cu(NO3)2⋅2.5H2O between 1.2° and 4.2°K by a ballistic method. Fields up to ... BE Myers,L Berger,SA Friedberg - 《J.appl...
(3), were prepared from Cu(NO3)2·2.5H2O and a combination of pyridinecarboxylic acid {4-pyridinecarboxylic (isonicotinic acid, inaH) or 3-pyridinecarboxylic (nicotinic acid, naH)} and multicarboxylic acid {1,3-benzenedicarboxylic acid (1,3-bdcH2) or 1,3,5-benzenetricarboxylic acid (1,3,...
Three discrete dinuclear copper(II)–lanthanide(III) complexes, namely, [CuLn(mmi)2(NO3)3(H2O)2] [Ln = La (1), Sm (2)] and [CuGd(mmi)2(NO3)2(H2O)3][NO3] (3... WX Zhang,YY Yang,SB Zai,... - 《European Journal of Inorganic Chemistry》 被引量: 33发表: 2008年 Magneticall...
A novel organic-inorganic hybrid material,[Cu(enMe)2(H2O)][{Cu(enMe)2}{Cu(enMe)2(H2O)W12O40(H2)}] centre dot nH2O (n = 0.33,enMe = 1,2-diaminopropane),has ... LLW He - 《Inorganic Chemistry Communications》 被引量: 0发表: 2007年 Outstanding Nobility Observed in Cu5 Clusters...
Intercalation chemistry of the novel layered double hydroxides [MAl4(OH)(12)](NO3)(2)center dot gamma H2O (M = Zn, Cu, Ni and Co). 2: Selective intercalati... The successful intercalation of a variety of organic dicarboxylates and sulfonates into the novel LDHs [MAl4(OH)12](NO 3)...
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