The scrambling due to the spinorbit coupling of the lowest excited singlet states 1T1g and 1T2g with 3T1g of diamagnetic Co(III) complexes is considered. Using a molecular orbital approach, this mixing is shown to account for the observed intensity of the 1A1g3T1g band. Specifically it ...
Dsp3,sp3,dsp2Submit Among ni(CO)4,[Ni(CN)4]2− and NiCI2−4 . Ani(CO)4 and NiCI2−4 are diamagnetic and [Ni(CN)4]2− is paramagnetic . BNiCI2−4 and [Ni(CN)2−4 are diamagnetic and Ni(CO)4 is paramagnetic . CNiCI2−4 and [Ni(CN)2−4 are diamagnetic and...
[Hg(C5H10NO2S)2] Negative ∗0 0 d10 Diamagnetic 7. Quasi-static thermo gravimetric analysis The QSTG analysis results of the complexes are very close to each other except the Hg(II) complex (Fig 3). The first step weight-loss is about 1.0–2.0% up to the decomposition point of each...
a. Ru(NH_3)_6^2+ (low-spin case). b. Ni(H_2O)_6^2+. c. V(en)_3^3+. Identify whether the given complex is diamagnetic or paramagnetic. If the complex is paramagnetic, further classify it as high spin or low spin and identify the number of unpaired electron...