The use of SAMs of ω-substituted alkylthiols (notably of sulfonates) on gold(111) surfaces for the room-temperature nucleation of monolayers of lepidocrocite (γ-FeO(OH); see diagram) from solution is presented.doi:10.1002/(SICI)1521-3765(19990401)5:4<1331::AID-CHEM1331>3.0.CO;...
Soft-chemical growth of 纬-FeO(OH) films on self-assembled monolayers of substituted alkylthiols on gold(111). Nagtegaal, Marc,Stroeve, Peter,Ensling, Juergen,Guetlich, Philipp,Schurrer, Matthias,Voit, Helmut,Flath, Johannes,Kaeshammer, Josua,Knoll, Wolfgang,Tremel, Wolfgang. Chemistry - A ...
contg. suspended needlelike gamma-FeO(OH) grains having narrow grain shape and grain size distributions is heated to 50-65 deg.C and kept at the temp., and by maintaining the pH value at 3.5-4.2, conditions forming no green rust I are established. In this state, oxidation is carried ...